DE is not calcareous at all, at least not the
UltraSorb, there may be trace amounts of calcium Carbonate in there but
Diatoms make their shell out of silicon dioxide. I think the closer you get to a pure DE deposit, the closer to a neutral PH you will get. I don't think you are going to find the PH specified on bags of DE sold as absorbent products, I only verified the PH of the UltraSorb by testing it with my PH meter.
You could use a horticultural grade DE which naturally would require it to be around a neutral PH, but at least around this area you are only going to find it sold at a hydro store in a granule size about like Perlite.